Search results for "Stille reaction"

showing 2 items of 2 documents

Synthesis of a novel ditopic ligand incorporating directly bonded 1,10-phenanthroline and 2,2′:6′,2″-terpyridine units

2006

Abstract The synthesis of a rigid ditopic ligand incorporating a 1,10-phenanthroline directly connected through its 3-position to the 5-position of a 2,2′:6′,2″-terpyridine is described. The synthesis is based on a series of palladium(0)-catalyzed cross-coupling reactions (Stille and Suzuki couplings) starting from 1,10-phenanthroline and bromo-substituted pyridines.

ChemistryLigandPhenanthrolineOrganic Chemistrychemistry.chemical_elementGeneral MedicineBiochemistryStille reactionchemistry.chemical_compoundDrug DiscoveryPolymer chemistryOrganic chemistryTerpyridinePalladiumTetrahedron Letters
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Triazolopyridines 23. Synthesis of 5,5'-bi[1,2,3]triazolo[5,1-a]isoquinoline

2003

5,5'-Bi[1,2,3]triazolo[5,1-a]isoquinoline 6 has been synthesised from [1,2,3]triazolo[5,1-a] isoquinoline 5 by four procedures, dimerisation by LDA, Stille and Suzuki self-coupling reactions, and Suzuki cross-coupling reaction. The last is the best. Compound 6 gives 1,1'bi(acetoxymethyl)-3,3'-biisoquinoline 10 by triazolo ring opening by acetic acid.

lcsh:QD241-441chemistry.chemical_compoundAcetic acidlcsh:Organic chemistrychemistryOrganic ChemistryIsoquinolineRing (chemistry)Medicinal chemistryStille reactionArkivoc
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